Chemistry - STEREO ISOMERISM Question with Solution | TestHub
Which of the following compounds has an asymmetric center?
(a) CH3CH2CH(F)CH3 (b) CH3CH2CH(CH3)CH2CH3 (c) CH3CH2CH(Cl)CH2CH2CH3
(d) (CH3)2CHCH2OH (e) CH3CH(NH2)CH2CH3 (f) CH3CH2CH2CH3
Options:
Answer:
Solution:
An asymmetric center is a carbon attached to four different groups.
(a) C2 of 2-fluorobutane carries H, F, CH3 and C2H5 : asymmetric. (b) C3 of 3-methylpentane carries two identical ethyl groups : not asymmetric. (c) C3 of 3-chlorohexane carries H, Cl, C2H5 and C3H7 : asymmetric. (d) The carbinyl carbon of 2-methylpropan-1-ol carries two methyls : not asymmetric. (e) C2 of butan-2-amine carries H, NH2, CH3 and C2H5 : asymmetric. (f) Butane has no such carbon.
Ans. (B) (a), (c) and (e).
