Chemistry - STEREO ISOMERISM Question with Solution | TestHub

ChemistrySTEREO ISOMERISMOPTICAL PURITY/ENANTIOMERIC EXCESS, POLARIMETER TUBE EXPERIMENTMedium2 minQB
ChemistryMediumsingle choice

Assertion :- D-configuration means rotate PPL in clockwise.

Reason :- Molecule will be dextrorotatory.

Options:

Answer:
D
Solution:

Question Explanation:

The question tests the relationship between D/L configuration and optical rotation

(dextrorotatory/levorotatory).

Concept:

D–L Configuration, Optical Activity, Plane Polarized Light (PPL).

Solution:

Assertion: (False)

“D-configuration means to rotate plane polarized light in a clockwise direction.”

D/L configuration is assigned based on the relative configuration with respect to glyceraldehyde,

not on the direction of rotation of plane polarized light.

Reason: (False)

“Molecule will be dextrorotatory.”

A molecule with D-configuration may be dextrorotatory (+) or levorotatory (–).

There is no fixed correlation between D/L notation and optical rotation.

Final Answer: Option (D)

Stream:JEESubject:ChemistryTopic:STEREO ISOMERISMSubtopic:OPTICAL PURITY/ENANTIOMERIC EXCESS, POLARIMETER TUBE EXPERIMENT
2mℹ️ Source: QB

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