Chemistry - STEREO ISOMERISM Question with Solution | TestHub

ChemistrySTEREO ISOMERISMASSIGNING RELATIONSHIPMedium2 minQB
ChemistryMediumsingle choice

Predict the correct relationship between given compounds :

(I) structure (II) structure (III) structure (IV) structure

Options:

Answer:
C
Solution:

Compound (I) is butan-2-one (a ketone) and compound (II) is 2-methylpropanal (an aldehyde). Compounds (III) and (IV) are the two geometrical (E/Z) enol forms of (I), not of (II); the enol of (II) would be 2-methylprop-1-en-1-ol. (I) and (II) are constitutional isomers (ketone vs aldehyde), not tautomers, and they give different enols. (II) and the enols (III), (IV) have the same molecular formula C4H8O but different functional groups (aldehyde vs enol), so they are functional isomers.

Ans. (C)

Stream:JEESubject:ChemistryTopic:STEREO ISOMERISMSubtopic:ASSIGNING RELATIONSHIP
⏱ 2mℹ️ Source: QB

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