Chemistry - STEREO ISOMERISM Question with Solution | TestHub
Which of the following compounds has an asymmetric center?
(a) CH3CH2CH(Cl)CH3 (b) CH3CH2CH(CH3)CH3 (c) CH3CH2C(CH3)(Br)CH2CH2CH3
(d) CH3CH2OH (e) CH3CH2CH(NH2)CH2CH3 (f) CH2=CHCH(Br)CH3
Options:
Answer:
Solution:
Ans. (A) (a), (c) and (f).
Sol. An asymmetric center is a carbon attached to four different groups.
(a) C2 of 2-chlorobutane carries H, Cl, CH3 and C2H5 : asymmetric.
(b) C2 of 2-methylbutane carries two CH3 groups : not asymmetric.
(c) C3 of 3-bromo-3-methylhexane carries Br, CH3, C2H5 and n-C3H7 : asymmetric.
(d) Ethanol has no carbon with four different groups.
(e) C3 of 3-aminopentane carries two C2H5 groups : not asymmetric.
(f) C3 of 3-bromobut-1-ene carries H, Br, CH3 and CH=CH2 : asymmetric.
