Chemistry - STEREO ISOMERISM Question with Solution | TestHub

ChemistrySTEREO ISOMERISMABSOLUTE AND RELATIVE CONFIGURATIONMedium2 minQB
ChemistryMediumsingle choice

Indicate whether each of the structures in the second row is an enantiomer of, is a diastereomer of, or is identical to the structure in the top row.

structure

(A) structure (B) structure

(C) structure (D) structure

Options:

Answer:
B
Solution:

The top structure is trans-1,2-dimethylcyclopropane, (1R,2R), which is chiral.

A: the same trans isomer redrawn (ring numbered from the other carbon) - same configuration at both centres : identical.

B: both centres inverted, (1S,2S) - the non-superimposable mirror image : enantiomer.

C: cis-1,2-dimethylcyclopropane, (1R,2S) meso - one centre retained, one inverted : diastereomer.

D: same (1R,2R) drawing as the top structure : identical.

Ans. (B) A - identical, B - enantiomer, C - diastereomer, D - identical.

Stream:JEESubject:ChemistryTopic:STEREO ISOMERISMSubtopic:ABSOLUTE AND RELATIVE CONFIGURATION
⏱ 2mℹ️ Source: QB

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