Chemistry - STEREO ISOMERISM Question with Solution | TestHub

ChemistrySTEREO ISOMERISMABSOLUTE AND RELATIVE CONFIGURATIONHard2 minQB
ChemistryHardmatching list

Match the following :

Column I (Compound)

Column II (Number of stereocenter)

(A) structure

(P) 4

(B) structure

(Q) 1

(C) structure

(R) 3

(D) structure

(S) Shows G.I.

Options:

Answer:
D
Solution:

Ans. A S; B P, S; C S; D R, S.

Sol. A (2-bromocyclohexan-1-ol): C-1 (OH) and C-2 (Br) are stereocentres (2 centres - not listed); cis/trans forms exist, so it shows geometrical isomerism : S.

B (2,3,4,5-tetramethylcyclohexan-1-one): the four methyl-bearing ring carbons C-2, C-3, C-4 and C-5 each carry four different groups : 4 stereocentres; it also shows geometrical isomerism : P, S.

C (1,2-dimethylcyclopentane): C-1 and C-2 are stereocentres (2 centres - not listed); cis/trans forms exist : S.

D (2,3,5-trimethylcyclopentan-1-one): C-2, C-3 and C-5 are stereocentres : 3 stereocentres; cis/trans forms exist : R, S.

Stream:JEESubject:ChemistryTopic:STEREO ISOMERISMSubtopic:ABSOLUTE AND RELATIVE CONFIGURATION
⏱ 2mℹ️ Source: QB

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