Chemistry - STEREO ISOMERISM Question with Solution | TestHub

ChemistrySTEREO ISOMERISMCONFORMATIONAL ISOMERISMMedium2 minQB
ChemistryMediumsingle choice

Rank the following conformations of 1,2-dibromoethane in order of increasing energy :

(I) structure (II) structure

(III) structure (IV) structure

Options:

Answer:
A
Solution:

IV is anti (Br-C-C-Br dihedral 180°) : no eclipsing, no gauche Br↔Br strain - lowest energy. I is gauche (staggered, but Br↔Br gauche steric strain) - next. III is partially eclipsed (two Br↔H eclipses and one H↔H eclipse). II is fully eclipsed with Br eclipsing Br - the highest energy. Hence IV I III II.

Stream:JEESubject:ChemistryTopic:STEREO ISOMERISMSubtopic:CONFORMATIONAL ISOMERISM
⏱ 2mℹ️ Source: QB

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