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ChemistrySolid StatePacking in lonic SolidsHard2 minPYQ_2018
ChemistryHardnumerical

Consider an ionic solidMX, withNaClstructure. Construct a new structureZ, whose unit cell is constructed from the unit cell ofMX, following the sequential instructions given below. Neglect the charge balance.
(i)Remove all the anionsX, except the central one.
(ii)Replace all the face centered cationsM, by anionsX.
(iii)Remove all the corner cationsM.
(iv)Replace the central anionX, with cationM.
The value ofnumber of anionsnumber of cationsinZis _____.

Answer:
3.00
Solution:

X-O.V
M+FCC

 M+X^-
(i)41
(ii)4 – 33 + 1
(iii)4 – 3 – 13 + 1
(iv)13

Z=31=3.

Stream:JEE_ADVSubject:ChemistryTopic:Solid StateSubtopic:Packing in lonic Solids
2mℹ️ Source: PYQ_2018

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