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ChemistryPRACTICAL ORGANIC CHEMISTRYDIFFERENTIATION, SEPARATION AND PURIFICATION of ORGANIC COMPOUNDSMedium2 minPYQ_2024
ChemistryMediumsingle choice

Match List I with List II

 LIST I (Technique) LIST II (Application)
A.DistillationI.Separation of glycerol from spent-lye
B.Fractional distillationII.Aniline - Water mixture
C.Steam distillationIII.Separation of crude oil fractions
D.Distillation under reduced pressureIV.Chloroform-Aniline

Choose the correct answer from the options given below:

Options:

Answer:
B
Solution:

A mixture of chloroform and aniline can be separated by distillation. The boiling point of chloroform is 60°C, and that of aniline is 189°C. Therefore, distillation can be used to separate a mixture of chloroform and aniline.

Fractional distillation is the process by which oil refineries separate crude oil into different, more useful hydrocarbon products based on their relative molecular weights in a distillation tower.

Steam Distillation is a separation process for temperature-sensitive substances. It is a particular type of distillation. Another way around is a method for separating miscible liquid bases depending upon their volatilities. Aniline - Water mixture can be separated by this technique.

For separating glycerol from spent-lye is distillation under reduced pressure because glycerol has a high boiling point and since in this method the external pressure is lowered, it boils at a lower temperature.

Hence option B is the answer.

Stream:JEESubject:ChemistryTopic:PRACTICAL ORGANIC CHEMISTRYSubtopic:DIFFERENTIATION, SEPARATION AND PURIFICATION of ORGANIC COMPOUNDS
2mℹ️ Source: PYQ_2024

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