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ChemistryPRACTICAL ORGANIC CHEMISTRYELEMENTAL ANALYSISMedium2 minPYQ_2022
ChemistryMediumsingle choice

In Carius method of estimation of halogen.0.45 gof an organic compound gave0.36 gofAgBr. Find out the percentage of bromine in the compound.
(Molar masses :AgBr=188 g mol-1:Br=80 g mol-1)

Options:

Answer:
A
Solution:

The Carius halogen method in analytical chemistry is a method for the quantitative determination of halogens in chemical substances. A known mass of an organic compound is heated with fuming nitric acid in the presence of silver nitrate contained in a hard glass tube known as Carius tube, in a furnace.

Mass of organic compound =0.45gm

Mass of AgBr obtained =0.36gm

Moles of AgBr=0.36188

Mass of Bromine =0.36188×80=0.1532gm

 % Br in compound =0.15320.45×100=34.04%

Stream:JEESubject:ChemistryTopic:PRACTICAL ORGANIC CHEMISTRYSubtopic:ELEMENTAL ANALYSIS
2mℹ️ Source: PYQ_2022

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