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ChemistryNomenclatureMiscellaneous/MixedMedium2 minPYQ_2024
ChemistryMediumsingle choice

Given below are two statements:

Statement I: IUPAC name of HO-CH2-(CH2)3-CH2-COCH3 is 7-hydroxyheptan-2-one.

Statement II: 2-oxoheptan-7-ol is the correct IUPAC name for the above compound.

In the light of the above statements, Choose the most appropriate answer from the options given below:

Options:

Answer:
A
Solution:

Rule 1 :- The longest chain in the molecule will be the parent chain. So, the first thing one should do is to find the longest carbon chain in the molecule.

Rule 2 :- Find out all the substituents present on the carbon chain. It can be any- from methyl to any alcohol substituent.

Rule 3 :- Start numbering the parent chain from the end such that the substituent gets the lowest number. This is called the lowest locant rule.

Rule 4 :- If the substituent occurs more than one time, then the prefix di, tri or tetra is being used with the location of the carbon on which it is present.

Rule 5 :- If more than one substituents are present and they are different. So, these will be named in alphabetical order.

In the given compound, hydroxy group is given at position 7, there is keto group at position 2, carbon chain consists of 7 carbon atoms, hence, it is heptane.

7-Hydroxyheptan-2- One is the correct IUPAC name.

Stream:JEESubject:ChemistryTopic:NomenclatureSubtopic:Miscellaneous/Mixed
2mℹ️ Source: PYQ_2024

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