Chemistry - Ionic Equilibrium Question with Solution | TestHub

ChemistryIonic EquilibriumMiscellaneous/MixedEasy2 minPYQ_2020
ChemistryEasynumerical

Bromine in excess is dropped to a 0.01 M SO2. All ofSO2is oxidized toH2SO4and the excessBr2is removed by flushing with gaseousN2. Determine the pH of the resulting solution assumingKa1ofH2SO4very large & K a2 = 10 −2 . Take the value oflog (3.24) = 0.51.

Answer:
1.49
Solution:





HSO 4 − 0.01-x aq ⇌ H + 0.03+x aq + SO 4 2+ x ;  Ka 2 = 10 −2

Ka 2 = 10 −2 = x 0.03+x 0.01−x

x=2.36× 10 −3 =0.00236

H + Total =0.03+0.00236

=0.03236=3.24+0.00236

pH=−log3.240× 10 −2

=2−log3.24=1.49

Stream:NTA_ABHYASSubject:ChemistryTopic:Ionic EquilibriumSubtopic:Miscellaneous/Mixed
⏱ 2mℹ️ Source: PYQ_2020

Doubts & Discussion

Loading discussions...