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ChemistryIdeal GasVapour PressureEasy2 minQB
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A volume of 4 l H₂O is placed in a closed evacuated room of volume 410.5 l at the temperature 300 K. The density of liquid water at 300 K is 1.0 g/ml. The vapour pressure of water at 300 K is 45.6 mm Hg. Neglect the change in volume of liquid water by vaporization.

Column I

Column II

A) Mass of water vapour formed (in g)

P) 4

B) Moles of water vapour formed

Q) 18

C) Approximately mass of liquid water left (in kg)

R) 3

D) Total moles of atoms in vapour form

S) 1

Options:

Answer:
C
Solution:

The vapour fills the room at P = 45.6/760 = 0.06 atm, so n = PV/RT = (0.06 × 410.5)/(0.0821 × 300) ≈ 1.0 mol (BS). Mass of vapour = 1 × 18 = 18 g (AQ). Moles of atoms in vapour = 3 × 1 = 3 mol (DR). Liquid water initially = 4000 g; after losing 18 g about 3982 g ≈ 4 kg is left (CP). Hence AQ; BS; CP; DR.

Stream:JEESubject:ChemistryTopic:Ideal GasSubtopic:Vapour Pressure
⏱ 2mℹ️ Source: QB

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