When isobutane is monochlorinated in the presence of ultra-violet light, the product obtained in higher yield is

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CH₃–CH(CH₃)–CH₃ C l 2 ​ / h ν ​ CH₃–CH(CH₃)–CH₂Cl + CH₃–C(CH₃)₂–Cl ∴ t er t b u t y l c h l or i d e i so b u t y l c h l or i d e ​ = n o . o f 3 ∘ H × re a c t i v i t yo f 3 ∘ H n o . o f 1 ∘ H × re a c t i v i t yo f 1 ∘ H ​ = 1 9 ​ × 5 1 ​

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