Chemistry - Halogen Derivative Question with Solution | TestHub
How many of the statement(s) are correct
i) The nucleophile makes a rear attack inreaction and expels the leaving group from front side.
ii)adds toaccording to Anti‐Markownikoff’s rule.
iii) The basicity of halides decreases in the orderbut the nucleophillicity is reverse of it. (in polar protic solvents)
iv) The rate ofreaction is independent of the polarity of the solvent.
v) Sigma complex or arenium ion is resonance stablised.
Answer:
Solution:
i) The nucleophile makes a rear attack inreaction and expels the leaving group from front side.
iii) The basicity of halides decreases in the orderbut the nucleophillicity is reverse of it. (in polar protic solvents)
v) Sigma complex or arenium ion is resonance stablised.
The above statements are correct.
adds toaccording to Markownikoff’s rule.
iv) The rate ofreaction is faster in polar aprotic solvent.