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ChemistryHalogen DerivativeNUCLEOPHILIC SUBSTITUTION REACTIONS (SN1 AND SN2), SN(NEIGHBOURING GROUP PARTICIPATION), SNIHard2 minPYQ_2014
ChemistryHardsingle choice

The major product formed when 1, 1, 1- trichloropropane is treated with aqueous potassium hydroxide is :

Question diagram: The major product formed when 1, 1, 1- trichloropropane is t

Options:

Answer:
C
Solution:

The major product formed when 1, 1, 1-trichloro-propane is treated with aqueous potassium hydroxide is propionic acid.

Alc. KOH causes elimination in the molecule of haloalkane generally, while aq. KOH leads to substitution. Here aqueous KOH is used, substitution reaction is most preferable.

The initial reaction is the nucleophilic substitution, which will form a trihydroxy compound, since, three hydroxy group on one carbon is unstable and result in dehydration and form carboxylic acid.

Stream:JEESubject:ChemistryTopic:Halogen DerivativeSubtopic:NUCLEOPHILIC SUBSTITUTION REACTIONS (SN1 AND SN2), SN(NEIGHBOURING GROUP PARTICIPATION), SNI
2mℹ️ Source: PYQ_2014

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