Chemistry - GOC Question with Solution | TestHub

ChemistryGOCAromaticityMedium2 minQB
ChemistryMediumsingle choice

Why is compound A (phenanthrene) more stable than compound B (anthracene) ?

(A) structure (B) structure

Options:

Answer:
A
Solution:

In the most stable Kekulé structure of phenanthrene the two outer rings are both benzene sextets, so it keeps two intact benzene units (resonance energy about 92 kcal/mol). In anthracene only one outer ring can be a full sextet at a time, so its resonance energy (about 84 kcal/mol) is smaller, and phenanthrene is more stable.

Stream:JEESubject:ChemistryTopic:GOCSubtopic:Aromaticity
⏱ 2mℹ️ Source: QB

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