Chemistry - GOC Question with Solution | TestHub

ChemistryGOCAromaticityMedium2 minQB
ChemistryMediumsingle choice

Why is compound A (triphenylene) much more stable than compound B (phenanthrene) ?

(A) structure

(B) structure

Options:

Answer:
A
Solution:

In triphenylene, all three outer rings are benzene sextets and the central ring has no extra double bond, so it has three intact benzene rings (about 108 kcal/mol). In phenanthrene only two intact benzene rings (72 kcal/mol) coexist with the central 9,10 double bond, so its total resonance energy (92 kcal/mol) is smaller than that of triphenylene.

Stream:JEESubject:ChemistryTopic:GOCSubtopic:Aromaticity
⏱ 2mℹ️ Source: QB

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