Chemistry - GOC Question with Solution | TestHub

ChemistryGOCRESONANCE AND MESOMERIC EFFECTMedium2 minQB
ChemistryMediumsingle choice

The pentadienyl anion has 6 pi electrons in five pi MOs. Which of the following MOs is the best representation of its LUMO ?

Options:

Answer:
B
Solution:

The 6 electrons fill the three lowest MOs (psi1, psi2, psi3). The LUMO is psi4, the fourth orbital, which has three nodes. Its phases alternate as +, -, (node), +, - , with no lobe on the central carbon.

Only option (B) has this pattern.

Stream:JEESubject:ChemistryTopic:GOCSubtopic:RESONANCE AND MESOMERIC EFFECT
⏱ 2mℹ️ Source: QB

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