Chemistry - GOC Question with Solution | TestHub

ChemistryGOCAcid BaseHard2 minQB
ChemistryHardsingle choice

Which of the following indicated H-atoms is most acidic in nature?

structure

Options:

Answer:
A
Solution:

Removing H_a (gamma to the carbonyl) gives a carbanion at the end of the conjugated O=C-C=C system : the charge delocalises through the diene unit onto the carbonyl oxygen (a vinylogous enolate, charge finishing on O). H_b is an ordinary α proton whose anion delocalises over only one carbonyl, H_c is a plain beta C-H with no resonance stabilisation, and H_d is vinylic and very hard to remove. The most stabilised conjugate base comes from H_a, so H_a is the most acidic.

Stream:JEESubject:ChemistryTopic:GOCSubtopic:Acid Base
⏱ 2mℹ️ Source: QB

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