Chemistry - GOC Question with Solution | TestHub

ChemistryGOCAcid BaseMedium2 minQB
ChemistryMediumsingle choice

Compare the two protons and shown in the following compound and identify which proton is more acidic.

structure

Options:

Answer:
A
Solution:

Removing gives the central carbanion : structure

Removing gives the α carbanion : structure

Both charges are on carbon, so compare resonance : the first anion is flanked by two carbonyls and the charge is delocalised over two oxygens, while the second is delocalised over only one carbonyl. More delocalisation means a more stable conjugate base, so the central proton is more acidic.

Stream:JEESubject:ChemistryTopic:GOCSubtopic:Acid Base
⏱ 2mℹ️ Source: QB

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