Chemistry - GOC Question with Solution | TestHub

ChemistryGOCAromaticityMedium2 minQB
ChemistryMediumsingle choice

Why is [18]annulene more stable than [14]annulene ?

(a) structure

(b) structure

Options:

Answer:
A
Solution:

Both rings have 4n + 2 π electrons (14 and 18). [14]Annulene has four inner H atoms that clash and force the ring out of plane. [18]Annulene has six inner H atoms spread around a much larger ring, so they do not clash and the ring is nearly planar and fully aromatic.

Stream:JEESubject:ChemistryTopic:GOCSubtopic:Aromaticity
⏱ 2mℹ️ Source: QB

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