Chemistry - GOC Question with Solution | TestHub

ChemistryGOCBond Length, Strength, Cleavage, Rotational Energy BarrierEasy2 minQB
ChemistryEasysingle choice

Compare the bond lengths of the indicated bonds in the given compounds :

structure structure

Options:

Answer:
A
Solution:

Both bonds are C-N bonds. In the second compound the N lone pair is pushed through the C=C onto the CHO group (a -M group, push-pull system), so the C-N bond has more double-bond character and is shorter. So a b.

Stream:JEESubject:ChemistryTopic:GOCSubtopic:Bond Length, Strength, Cleavage, Rotational Energy Barrier
⏱ 2mℹ️ Source: QB

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