Chemistry - GOC Question with Solution | TestHub

ChemistryGOCHyper conjugationMedium2 minQB
ChemistryMediumsingle choice

Compare positive magnitudes of the total molar heats released on complete hydrogenation of the compounds (not heat per double bond):

(1) Electronic Displacement Effect diagram 2615 (2) Electronic Displacement Effect diagram 2616 (3) Electronic Displacement Effect diagram 2617 (4) Electronic Displacement Effect diagram 2618

Options:

Answer:
D
Solution:

Here heat of hydrogenation is compared per of the complete compound, not per double bond. As the number of reducible double bonds increases from 4 to 1, more heat is released overall despite resonance stabilization. The source's magnitude order is 4 < 3 < 2 < 1. State magnitude rather than signed enthalpy.

Stream:JEESubject:ChemistryTopic:GOCSubtopic:Hyper conjugation
⏱ 2mℹ️ Source: QB

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