Chemistry - GOC Question with Solution | TestHub

ChemistryGOCAromaticityEasy2 minQB
ChemistryEasysingle choice

Which is stable and can be isolated : cycloheptatrienone or cyclopentadienone ?

Options:

Answer:
D
Solution:

The C=O group is polarised (C+ O-). In cycloheptatrienone the ring in this resonance form is the tropylium cation (6 π electrons, aromatic). In cyclopentadienone it is the cyclopentadienyl cation (4 π electrons, anti-aromatic), so the molecule is very reactive and cannot be isolated.

Stream:JEESubject:ChemistryTopic:GOCSubtopic:Aromaticity
⏱ 2mℹ️ Source: QB

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