Chemistry - GOC Question with Solution | TestHub

ChemistryGOCAromaticityMedium2 minQB
ChemistryMediumsingle choice

In which of the following pairs does the first compound (I) have more resonance energy than the second (II) ?

(A) (I) structure (II) structure

(B) (I) structure (II) structure

(C) (I) structure (II) structure

(D) (I) structure (II) structure

Options:

Answer:
B
Solution:

(A) butadiene is acyclic and has far less resonance energy than benzene. (B) pyrrole (resonance energy about 21 kcal/mol) has more resonance energy than furan (about 16 kcal/mol) : correct. (C) the cyclohexadienyl cation (4π, anti-aromatic when planar) is destabilised, while the tropylium cation is aromatic (6π). (D) cyclooctatetraene is non-planar with almost no resonance, while styrene has a benzene ring. So (B).

Stream:JEESubject:ChemistryTopic:GOCSubtopic:Aromaticity
⏱ 2mℹ️ Source: QB

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