Chemistry - GOC Question with Solution | TestHub
ChemistryGOCAromaticityMedium2 minQB
ChemistryMediumsingle choice
Which of the following reactions will NOT proceed ?
(A)
+ S
(B)
+ 2 BuLi
(C)
(-HCl)
(D)
(1)
Options:
Answer:
D
Solution:
(A) S removes and gives the aromatic cyclopropenyl cation. (B) 2 BuLi removes both chlorines to give the pentalene dianion (10π, aromatic). (C) loss of HCl leads to the aromatic tropone system. (D) ₁ would need the cyclopentadienyl cation (4π, anti-aromatic), which is very unstable, so the reaction does not proceed.
Stream:JEESubject:ChemistryTopic:GOCSubtopic:Aromaticity
⏱ 2mℹ️ Source: QB
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