Chemistry - GOC Question with Solution | TestHub

ChemistryGOCAromaticityMedium2 minQB
ChemistryMediumsingle choice

Which of the following reactions will NOT proceed ?

(A) structure + S

(B) structure + 2 BuLi

(C) structure (-HCl)

(D) structure (1)

Options:

Answer:
D
Solution:

(A) S removes and gives the aromatic cyclopropenyl cation. (B) 2 BuLi removes both chlorines to give the pentalene dianion (10π, aromatic). (C) loss of HCl leads to the aromatic tropone system. (D) ₁ would need the cyclopentadienyl cation (4π, anti-aromatic), which is very unstable, so the reaction does not proceed.

Stream:JEESubject:ChemistryTopic:GOCSubtopic:Aromaticity
⏱ 2mℹ️ Source: QB

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