Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistryWerner theory + calculation of EANHard2 minQB
ChemistryHardmultiple choice

A salt contains one trivalent metal M, potassium and six nitrite units per formula. It produces four ions per formula unit on complete dissociation, with total positive ionic charge +3 and total negative ionic charge −3. All six nitrites are coordinated monodentately; M is low-spin d⁶. Which follow? Count donor-mode/geometrical forms in an ideal octahedron.

Options:(select one or more)

Answer:
A, B, C
Solution:

Three K⁺ ions and one complex anion account for four particles and charges ±3. M³⁺ plus six nitrites gives −3. Low-spin d⁶ is paired. N-bound ligand counts 0…6 give 1,1,2,2,2,1,1 geometrical forms, total ten. None of the binary monodentate Ma₆₋ₖbₖ arrangements is chiral, so D is false.

Stream:JEESubject:ChemistryTopic:Coordination ChemistrySubtopic:Werner theory + calculation of EAN
⏱ 2mℹ️ Source: QB

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