Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistryVBT,CFT(complex compound)Easy2 minQB
ChemistryEasyinteger

How many of the following salts contain a paramagnetic octahedral anion? K₃[CoF₆], K₃[Fe(CN)₆], K₄[Fe(CN)₆], K₂[PtCl₆], K₃[Cr(ox)₃], Na₃[Co(NO₂)₆], K₂[NiCl₄], K₄[Mn(CN)₆]

Answer:
4
Solution:

Paramagnetic octahedral anions: [CoF₆]³⁻ (4 unpaired), [Fe(CN)₆]³⁻ (1), [Cr(ox)₃]³⁻ (3) and [Mn(CN)₆]⁴⁻ (1). [Fe(CN)₆]⁴⁻, [PtCl₆]²⁻ and [Co(NO₂)₆]³⁻ are diamagnetic, and [NiCl₄]²⁻ is tetrahedral. Count = 4.

Stream:JEESubject:ChemistryTopic:Coordination ChemistrySubtopic:VBT,CFT(complex compound)
⏱ 2mℹ️ Source: QB

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