Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistryIntroduction, About ligandMedium2 minQB
ChemistryMediumsingle choice

Find the number of ligands which are neutral & bidentate ligands among the following -

(a) en     (b) bn     (c) tn        (d) pn     (e) dimethylglyoximato         (f) ox 

(g)acac (acetylacetanato)    (h) ethylenediaminetetraacetato

Options:

Answer:
A
Solution:

 

The neutral and bidentate ligands are:

(a) en (ethylenediamine): Neutral, bidentate.

(b) bn (1,2-diaminopropane or propylenediamine): Neutral, bidentate.

(c) tn (1,3-diaminopropane or trimethylenediamine): Neutral, bidentate.

(d) pn (1,2-diaminopropane or propylenediamine): Neutral, bidentate.

 

(e) dimethylglyoximato (dmg⁻): Anionic, bidentate.

(f) ox (oxalate, C₂O₄²⁻): Anionic, bidentate.

(g) acac (acetylacetonato, acac⁻): Anionic, bidentate.

(h) ethylenediaminetetraacetato (EDTA⁴⁻): Anionic, hexadentate.

 

Thus, there are 4 neutral and bidentate ligands.

 

The final answer is .

Stream:JEESubject:ChemistryTopic:Coordination ChemistrySubtopic:Introduction, About ligand
2mℹ️ Source: QB

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