Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistryIsomerismHard2 minQB
ChemistryHardinteger

The octahedral complex [Co(gly)₂(NO₂)(SCN)]⁻ has two ambidentate monodentate ligands, NO₂⁻ (N or O) and SCN⁻ (S or N), and two unsymmetrical glycinate chelates. Find the total number of isomers, counting linkage forms and stereoisomers.

Answer:
44
Solution:

Four linkage forms arise from the two ambidentate ligands (2 × 2). Each form is M(AB)₂bc, which has 11 stereoisomers. Total = 4 × 11 = 44.

Stream:JEESubject:ChemistryTopic:Coordination ChemistrySubtopic:Isomerism
⏱ 2mℹ️ Source: QB

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