A C 4 H 8 Cl 2 → 373 K Hydrolysis B C 4 H 8 O B reacts with Hydroxyl amine but does not give Tollen's test. Identify A and B .

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ChemistryCoordination ChemistryIntroduction, About ligandMedium2 minPYQ_2021

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$\underset{(C_{4} H_{8} {Cl}_{2})}{A} \to_{373 K}^{Hydrolysis} \underset{(C_{4} H_{8} O)}{B}$

$B$ reacts with Hydroxyl amine but does not give Tollen's test. Identify $A$ and $B$ .

Answer:

Solution:

Aldehydes and ketones react with hydroxyl amine to form oximes but ketones do not react with Tollens reagent.

Compound ${}^{'}B^{'}$ does not gives Tollen's test due to presence of kenotic group but react with hydroxyl amine

Stream:JEESubject:ChemistryTopic:Coordination ChemistrySubtopic:Introduction, About ligand

⏱ 2mℹ️ Source: PYQ_2021

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