Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistryMiscellaneous/MixedEasy2 minPYQ_2020
ChemistryEasysingle choice

Given the molecular formula of the hexacoordinate complexes

A    CoCl 3 ·6  NH 3 B    CoCl 3 ·5  NH 3 C    CoCl 3 ·4  NH 3

If the number of coordinated NH3molecules in A, B and C respectively are 6, 5 and 4, the primary valency in (A), (B) and (C) are -

Options:

Answer:
A
Solution:

Co has six coordination number, hence formulae for compounds A, B and C should be
A   Co NH 3 6 Cl 3
B   Co NH 3 5 Cl Cl 2 NH 3
C   Co NH 3 4 Cl 2 Cl NH 3 2
Primary valency is equal to the oxidation state of the central metal ion.

Stream:NTA_ABHYASSubject:ChemistryTopic:Coordination ChemistrySubtopic:Miscellaneous/Mixed
⏱ 2mℹ️ Source: PYQ_2020

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