Chemistry - Complete P-block Question with Solution | TestHub

ChemistryComplete P-blockp-Block 15,16Easy2 minPYQ_2024
ChemistryEasymatching list

Choose the correct statements about the hydrides of group15elements.
A. The stability of the hydrides decreases in the orderNH3>PH3>AsH3>SbH3>BiH3
B. The reducing ability of the hydrides increases in the orderNH3<PH3<AsH3<SbH3<BiH3
C. Among the hydrides,NH3is strong reducing agent whileBiH3is mild reducing agent.
D. The basicity of the hydrides increases in the orderNH3<PH3<AsH3<SbH3<BiH3

 

Choose the most appropriate from the option given below:

Options:

Answer:
C
Solution:

On moving down the group from N to Bi, the atomic size increases. Consequently, the electron density on the central atom decreases and the basic strength decreases.

With an increase in size, the M-H bond becomes weaker, hence, the thermal stability decreases down the group.

The highest bond length will have less bond energy, indicating that it is a strong reducing agent.

On moving down the group, bond strength of M–H bond decreases, which reduces the thermal stability but increases reducing nature of hydrides,

Hence A and B are correct statements. 

Stream:JEESubject:ChemistryTopic:Complete P-blockSubtopic:p-Block 15,16
2mℹ️ Source: PYQ_2024

Doubts & Discussion

Loading discussions...