Derivative of nitrogen (III) act as

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Derivatives of nitrogen (III) has both oxidizing and reducing properties as it is having intermediate oxidation state

$\underset{(O x i d a n t)}{\overset{+ 3}{2 N a N O_{2}}} + 2 K I + 2 H_{2} S O_{4} \to I_{2} + 2 \overset{+ 2}{N O} + K_{2} S O_{4} + N a_{2} S O_{4} + 2 H_{2} O$

$2 K M n O_{4} + \underset{(Reductant)}{\overset{+ 3}{5 N a N O_{2}}} + 3 H_{2} S O_{4} \to 2 M n S O_{4} + 5 N a {\overset{+ 5}{N O}}_{3} + K_{2} S O_{4} + 3 H_{2} O$

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