Chemistry - Chemical Kinetics Question with Solution | TestHub

ChemistryChemical KineticsRate of Reactions/Rate LawEasy2 minPYQ_2020
ChemistryEasysingle choice

By using following mechanism determine the order of the reaction
(i)A2→A+A(fast)
iiA+B2→AB+B(slow)
(iii)A+B→(fast)

Options:

Answer:
A
Solution:

Slowest step is rate determining step, hence the rate will be given by slowest step.
Thusr=K[A][B2]. Where[A]is intermediate, which is derived from
Kc=[A][A][A2]or[A]=[Kc]1/2[A2]1/2
r=K×[Kc]1/2[A2]1/2[B2]=K[A2]1/2[B].
Thus, order is0.5+1=1.5

Stream:NTA_ABHYAS_NEETSubject:ChemistryTopic:Chemical KineticsSubtopic:Rate of Reactions/Rate Law
⏱ 2mℹ️ Source: PYQ_2020

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