Chemistry - Chemical Kinetics Question with Solution | TestHub

ChemistryChemical KineticsRate of Reactions/Rate LawEasy2 minPYQ_2020
ChemistryEasysingle choice

Reaction A + B → C + D follows rate law R = K[A]1/2 [B]1/2 starting with 1 M of A and B. What is time taken for concentration of A to become 0.1 M ? [Given, K = 4.606 x 10-4 s-1]   

Options:

Answer:
D
Solution:



R = K A 1 / 2 B 1 / 2

dx dt = K 1 - x 1 / 2 1 - x 1 / 2

dx dt = K 1 - x

Integrating on both sides

K = 2.303 t log 1 1 - x  , 

( ∴( 1-x )=0.1 M  at  time  t )

⇒ 4.606 × 1 0 - 4 = 2.303 t log 1 0.1 = 2.303 t

⇒ 2 × 1 0 - 4 = 1 t

 

or t = 1 0 4 2 = 1 0 0 0 0 2 = 5000 s

Stream:NTA_ABHYAS_NEETSubject:ChemistryTopic:Chemical KineticsSubtopic:Rate of Reactions/Rate Law
⏱ 2mℹ️ Source: PYQ_2020

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