Chemistry - Chemical Kinetics Question with Solution | TestHub

ChemistryChemical KineticsMiscellaneous/MixedEasy2 minPYQ_2020
ChemistryEasynumerical

The gas phase decomposition of dimethylether follows first order kinetics
CH3-O-CH3g→CH4g+H2g+COg
The reaction is carried out in constant volume container at500oCand has a half-life of 14.5 min . Initially only dimethylether is present at a pressure of 0.40 atm . The total pressure of the system after 12 min is x 100  atm . The value ofxis
[Given 10 0.25  = 1.778 ]

Answer:
75.00
Solution:



Now:12=2.3030.693×14.5log⁡0.40.4-x

0.25=log⁡0.40.4-x

100.25=0.40.4-x

0.40.4-x=1.778

⇒x=0.175

Total pressure=0.4-0.75+0.175+0.175+0.175=0.75 atm

now:x100=0.75

x=75

Stream:NTA_ABHYASSubject:ChemistryTopic:Chemical KineticsSubtopic:Miscellaneous/Mixed
⏱ 2mℹ️ Source: PYQ_2020

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