Chemistry - CHEMICAL BONDING Question with Solution | TestHub

ChemistryCHEMICAL BONDINGMOTHard2 minQB
ChemistryHardmultiple choice

In hypothetical N₂, suppress s–p mixing so σ<π<π*<σ*. Then add two electrons sequentially, following Hund's rule. Separately, imagine forcing the two π* electrons of the final dianion into the SAME component while all other occupancies remain fixed. Which statements are correct?

Options:(select one or more)

Answer:
A, B, D
Solution:

Neutral N₂ has 10 valence electrons and BO3. Both additions occupy antibonding π* orbitals, reducing BO to2.5 then2. Hund's rule distributes the two π* electrons singly with parallel spins. Pairing them changes spin and energy, not the number of antibonding electrons, so C is false. Both π* components are g, giving D even in the forced-pair excited arrangement.

Stream:JEESubject:ChemistryTopic:CHEMICAL BONDINGSubtopic:MOT
⏱ 2mℹ️ Source: QB

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