Chemistry - CHEMICAL BONDING Question with Solution | TestHub
In order to explain the characteristic geometrical shapes of polyatomic molecules like , and etc. pauling introduced the concept of hybridisation. According to him the atomic orbitals combine to form new set of equivalent orbitals known as hybrid orbitals. Unlike pure orbitals, the hybrid orbitals are used in bond formation. The phenomenon is known as hybridisation which can be defined as the process of intermixing of the orbitals of similar energies so as to redistribute their energies, resulting in the formation of set of new orbitals of equivalent energies and shape.
Which of the following set of molecule/ions have similar shape ?
Options:(select one or more)
Answer:
Solution:
(A) BrF4− , XeOF4
- BrF₄⁻ → square planar
- XeOF₄ → square pyramidal
Different shapes
(B) XeF6 , XeOF5−
- XeF₆ → distorted octahedral
- XeOF₅⁻ → distorted octahedral
Same shape
(C) Nitrite ion , Dichlorine monoxide
- NO₂⁻ → bent
- Cl₂O → bent
Same shape
(D) Sulfur tetrafluoride , XeO2F2
- SF₄ → see-saw
- XeO₂F₂ → see-saw
Same shape
