Chemistry - Carboxylic acid and their Derivatives Question with Solution | TestHub
Treatment of compound A with KMnO4 gave B, Which on heating with NH3 gave C. Compound C on treatment with Br2 /NaOH produced D. D reacts with NaNO2 + HCl followed by H3PO2 gave
The compound C is

Options:
Answer:
Solution:
The final product is isopropylbenzene, formed by the deamination of D (/HCl), followed by reaction with . This indicates D is an isopropylaniline.
Compound D is produced from C via Hofmann bromamide degradation (/NaOH), which converts an amide () to an amine (). Thus, C is p-isopropylbenzamide.
Working further back, C is formed from B (,Δ), meaning B is p-isopropylbenzoic acid.
B was formed by the oxidation of A, where a second alkyl group (like a methyl group in p-cymene) was oxidized to a carboxyl group.
Comparing this to the options, structure (C) is the correct representation of the amide p-isopropylbenzamide.