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ChemistryCarboxylic acid and their DerivativesPREPARATION OF CARBOXYLIC ACIDS AND THEIR DERIVATIVESMedium2 minPYQ_2019
ChemistryMediumsingle choice

The increasing order of the reactivity of the following with LiAlH4 is:

(A)

(B)

(C)

(D)

Question diagram: The increasing order of the reactivity of the following with

Options:

Answer:
C
Solution:

In the mentioned structures H- will get added to the carbon having slight positive charge.

Presence of Cl increases the positive charge whereas an electron donating group like NH2 decreases the tendency.

Rate of reaction -M or -I group

Rate of reaction 1+M and 1+I

Hence, the correct order will be:

Stream:JEESubject:ChemistryTopic:Carboxylic acid and their DerivativesSubtopic:PREPARATION OF CARBOXYLIC ACIDS AND THEIR DERIVATIVES
2mℹ️ Source: PYQ_2019

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