Chemistry - Carbonyl compounds Question with Solution | TestHub

ChemistryCarbonyl compoundsAldol condensation and Cannizzarro reactionMedium2 minQB
ChemistryMediummatching list

 

List - I

List - II

(Product or atleast one product)

(P) Product

(1) One of the product liberates when treated with

(Q) Product

(2) Nucleophilic addition or takes place during reaction

(R) Product

(3) One of the product contains halogen

(S) Product

(4) Baeyer Villiger oxidation reaction

 

(5) Cannizzaro's reaction

Options:

Answer:
C
Solution:

* (P) (2): Acetaldehyde (CH₃CHO) undergoes Aldol condensation in the presence of NaOH and heat, which proceeds via nucleophilic addition.

 

* (Q) (1): Benzaldehyde (PhCHO) undergoes Cannizzaro's reaction to form benzoic acid (PhCOOH), which liberates CO₂ when treated with NaHCO₃.

 

* (R) (4): Reaction of PhCHO with -CPBA is a Baeyer-Villiger oxidation that converts the aldehyde into a phenyl formate ester.

 

* (S) (3): Acetaldehyde reacts with NaOH/I₂ via the Haloform reaction to produce iodoform (CHI₃), which contains halogen atoms.

Stream:JEESubject:ChemistryTopic:Carbonyl compoundsSubtopic:Aldol condensation and Cannizzarro reaction
⏱ 2mℹ️ Source: QB

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