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ChemistryBiomoleculesAMINO ACIDMedium2 minPYQ_2022
ChemistryMediumnumerical

Optical activity of an enantiomeric mixture is+12.6°and the specific rotation of+isomer is+30°. The optical purity is____%

Answer:
42.00
Solution:

The "optical purity" is a comparison of the optical rotation of a pure sample of unknown stereochemistry versus the optical rotation of a sample of pure enantiomer. It is expressed as a percentage. If the sample only rotates plane-polarized light half as much as expected, the optical purity is 50%.

% optical purity =observed rotation of mixture×100rotation of pure enantiomer

=+12.6°+30°×100=42

Stream:JEESubject:ChemistryTopic:BiomoleculesSubtopic:AMINO ACID
2mℹ️ Source: PYQ_2022

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