Chemistry - AMINES Question with Solution | TestHub

ChemistryAMINESCHEMICAL REACTIONS OF AMINESMedium2 minQB
ChemistryMediumsingle choice

Benzylamine may be alkylated as shown in the following equation :

C₆H₅CH₂NH₂ + R—X → C₆H₅CH₂NHR

Which of the following alkylhalides is best suited for this reaction through SN1 mechanism?

Options:

Answer:
C
Solution:

An SN1 path requires a stable carbocation. C₆H₅CH₂Br ionises to the resonance-stabilised benzyl cation, so it reacts fastest by SN1. CH₃Br and C₂H₅Br form unstable 1° cations (SN2 only) and C₆H₅Br does not ionise (aryl C—Br).

Stream:JEESubject:ChemistryTopic:AMINESSubtopic:CHEMICAL REACTIONS OF AMINES
⏱ 2mℹ️ Source: QB

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