Chemistry - ALCOHOL & ETHER Question with Solution | TestHub

ChemistryALCOHOL & ETHERREACTIONS OF ALCOHOLS and ETHERSEasy2 minPYQ_2020
ChemistryEasysingle choice

Alcohol →P+I2 X →Mg, dry ether Y →HCHO Z →H2O/H+ 2-methylpropanol

In this sequence of reactions, the starting alcohol is

Options:

Answer:
B
Solution:

Alcohols on reaction with phosphorous iodide to give alkyl chloride. The product formed has a halogen atom attached to the same carbon which was attached to the hydroxy group.

The alkyl iodide formed reacts with Mg in presence of dry ether to form Grignard reagent, isopropyl magnesium iodide.

The Grignard reagent on reaction with formaldehyde gives 2-methylpropoxide ion.

2-methylpropoxide ion on acidic hydrolysis finally gives 2-methylpropanol.

Stream:NTA_ABHYAS_NEETSubject:ChemistryTopic:ALCOHOL & ETHERSubtopic:REACTIONS OF ALCOHOLS and ETHERS
⏱ 2mℹ️ Source: PYQ_2020

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